We are an active research group with highly motivated members in the field of Nanochemistry. Our current research activities include the design and synthesis of new silica/organosilica nanoparticles with especial morphology and novel porous organic polymers for CO2 capture and conversion. Want to join? Contact us!
MSc. Student of Nanochemistry
Email: tohidnouri@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistry
Email: niloofarabbassi@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistry
Email: rashvand.m@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistry
Email: mhmdasil@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistry
Email: neginhassani@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistri
Email: negin.aslani@iasbs.ac.ir
Tell: +982433153229
MSc. Student of Nanochemistry
(2017-2020)Email: masomeh.razaghi71@gmail.com
MSc. Student of Nanochemistry
(2019-2022)Email:sanazasgarloo757@gmail.com
MSc. Student of Nanochemistry
(2019-2023)Email: k.hoseini.firozkohi@gmail.com
Joint Student (Dr. Masoumeh Taherimehr)
MSc. Student of Analytical Chemistry
(Babol Noshirvani University of Technology)
Email: habibishahla0@gmail.com
Visiting Student
BSc. Student of Chemical Engineering
(University of Zanjan)
Email: student.arian.aa@gmail.com
MSc. Student of Nanochemistry
(2020-2024)Email: ghazaaaleee1375@gmail.com
MSc. Student of Nanochemistry
(2020-2024)Email: sadeghjoudian@gmail.com
MSc. Student of Nanochemistry
(2021-2024)Email: mozhde.p.mansouri@gmail.com
Covalent organic frameworks (COFs) are an advanced class of crystalline porous polymers. The COFs are typically prepared by direct reaction of at least two monomers bearing suitable functional groups resulting in strong, covalent bonds to afford porous, stable, and crystalline materials. Another class of porous organic polymers with high surface area functionalized by triazine heterocycle denoted as covalent triazine frameworks (CTFs), can be achieved either by dynamic trimerization reaction of aromatic nitriles or polymerization of organic monomers with triazine ring. Thanks to the high surface area, tunable pore size and diameter, high loading of organic functional groups, and relatively easy functionalization, COFs and CTFs have attracted much attention in catalysis.
Periodic mesoporous organosilicas (PMOs) are an advanced class of organic-inorganic hybrid materials. The PMOs are typically prepared by the hydrolysis and condensation of at least one bridged organosilane precursor [(R’O)3Si-R-Si(OR’)3] in the presence of a suitable surfactant as a structure-directing agent (SDA) under either acidic or basic conditions. Thanks to the high surface area, tunable pore size and diameter, high loading of organic functional groups, and easy functionalization of the inner surface and outer particles, PMOs have attracted much attention in the fields of catalysis.
Although a plethora of bulk mesoporous silicas/organosilicas functionalized by the desired catalyst has been reported so far, synthesis of the mesoporous catalyst with well-defined morphology such as spherical, hollow spheres, core-shell and hierarchical structures in the nanoscale domain, has continued to be a challenge. Among these structures, hollow sphere materials are considered as superior candidates for designing highly efficient catalytic systems for gas-phase reactions due to their capability for gas molecule up-taking and followed by enhancement of gas retention time around centers where the catalyst is located. Currently, we are conducting some research on introducing new hollow mesoporous catalysts for carbon dioxide valorization.
In recent years, human activities, the rapid growth of industrialization, and especially the uncontrolled combustion of fossil fuels have unfortunately resulted in the increase of atmospheric concentration of carbon dioxide, as a component of greenhouse gases. The long-term effects of this trend have ensued global warming, ice melting, ocean warming, sea-level rising, and ocean acidification which are overall defined as global climate change. Consequently, the development of new carbon capture and utilization systems which was able to minimize carbon dioxide emissions has become the hottest topic in the scientific communities. In this regard, we currently focused on designing new porous catalysts for the conversion of carbon dioxide to the value-added products.
22) Ghazale Anvarian-Asl, Sadegh Joudian, Stefano Todisco, Pietro Mastrorilli and Mojtaba Khorasani
Controllable synthesis of hollow mesoporous organosilica nanoparticles with pyridine-2,6-bis-imidazolium frameworks for CO2 conversion
Nanoscale, 2024, 16, 16977-16989.
Full Text >>>
21) Tohid Nouri and Mojtaba Khorasani
Nickel supported on mesoporous organosilica nanoparticles incorporating pyridine-based SNS ligand as an efficient recoverable catalyst for chemical fixation of CO2
Journal of Physical Chemistry C, 2024, 128, 166-176.
Full Text >>>
20) Ramin Jamali, Vahideh Farzam Rad, Masoumeh Razaghi, Zahra Mohamadnia, Mojtaba Khorasani and Ali-Reza Moradi
Digital holographic microscopy of spiropyran-based dynamic materials
Journal of Microscopy, 2023, 292, 78-89.
Full Text >>>
19) Kosar Sadat Hoseini, Masoumeh Razaghi, Tohid Nouri and Mojtaba Khorasani
Direct coupling of CO2 with epoxides catalyzed by lanthanum(III) supported on magnetic mesoporous
organosilica nanoparticles
Scientific Reports, 2023, 404, 5521.
Full Text >>>
18) Masoumeh Razaghi, Mojtaba Khorasani, Zahra Mohamadnia and Foad Kazemi
Coupling of hydrophobic graphene quantum dots with photochromic molecule for fabrication of transparent photo-responsive polymeric films manifesting FRET functioning
Journal of Photochemistry and Photobiology A: Chemistry, 2023, 437, 114420Full Text >>>
17) Mojtaba Khorasani, Babak Karimi and Hojatollah Vali
Coupling of CO2 with epoxides catalyzed by bifunctional periodic mesoporous organosilica with ionic liquid framework
Reaction Chemistry & Engineering, 2022, 7, 2618-2628
Full Text >>>
16) Masoumeh Razaghi, Mojtaba Khorasani
Boosting the quaternary ammonium halides catalyzed CO2 coupling with epoxides on the hollow mesoporous silica sphere
Journal of CO2 Utilization, 2022, 61, 102028. Full Text >>>
15) Kobra Zavar Mousavi, Yadollah Yamini, Babak Karimi, Mohammad Mahdi Khataei, Mojtaba Khorasani, Shahram Seidi and Mostafa Ghaemmaghami
Plugged bifunctional periodic mesoporous organosilica as a high-performance solid phase microextraction coating for improving extraction efficiency of chlorophenols in different matrices
Talanta, 2021, 235, 122724. Full Text >>>
14) Majid Panahi, Ramin Jamali, Vahideh Farzam Rad, Mojtaba Khorasani, Ahamd Darudi and Ali-Reza Moradi
3D monitoring of the surface slippage effect on micro-particle sedimentation by digital holographic microscopy
Scientific Reports, 2021, 11, 12916. Full Text >>>
13) Babak Karimi, Akram Bigdeli, Ali Asghar Safari, Mojtaba Khorasani, Hojatollah Vali and Somaiyeh Khodadadi Karimvand
Aerobic oxidation of alcohols catalyzed by in situ generated gold nanoparticles inside the channels of periodic mesoporous organosilica
with ionic liquid framework
ACS Combinatorial Science, 2020, 22, 70-79. Full Text >>>
12) Kobra Zavar Mousavi, Yadollah Yamini, Babak Karimi, Shahram Seidi, Mojtaba Khorasani, Mostafa Ghaemmaghami and Hojatollah Vali
Imidazolium-based mesoporous organosilicas with bridging organic groups for microextraction by packed sorbent of phenoxy acid herbicides, polycyclic aromatic hydrocarbons and chlorophenols
Microchimica Acta, 2019, 186, 239-248. Full Text >>>
11) Babak Karimi, Omolbanin Yari, Mojtaba Khorasani, Hojatollah Vali, Fariborz Mansouri
Aerobic oxidative dehydrogenation of amines catalysed by a recoverable ruthenium catalyst under mild reaction conditions
ChemCatChem, 2018, 10, 1783-1787. Full Text >>>
10) Babak Karimi, Zahra Naderi, Mojtaba Khorasani, Hamid Mohammad Mirzaie and Hojatollah Vali
Ultra-small platinum nanoparticles supported inside the nanospaces of PMO with imidazolium network: an efficient catalyst for aerobic oxidation of
non-activated alcohols in water, ChemCatChem, 2016, 8, 906-910. Full Text >>>
9) Babak Karimi, Fariborz Mansouri and Mojtaba Khorasani
Recent Progress in Design and Application of Functional Ordered/Periodic Mesoporous Silicas (OMSs) and Organosilicas (PMOs) as Catalyst Support in Carbon-Carbon Coupling Reactions, Current Organic Chemistry, 2015, 20, 349-380.
Full Text >>>
8) Mohammad Gholinejad, Babak Karimi, Afsaneh Aminianfar and Mojtaba Khorasani
One pot preparation of propargylamines catalyzed by heterogeneous copper catalyst supported on periodic mesoporous organosilica with ionic liquid framework
ChemPlusChem, 2015, 80, 1573-1579. Full Text >>>
7) Babak Karimi, Mojtaba Khorasani, Fatemeh Bakhshandeh Rostami, Dawood Elhamifar and Hojatollah Vali
Tungstate supported on periodic mesoporous organosilica with imidazolium framework as an efficient and recyclable catalyst for the selective oxidation of sulfides
ChemPlusChem, 2015, 80, 990-999. Full Text >>>
6) Babak Karimi, Mojtaba Khorasani, Hojatollah Vali, Carolina Vargas and Rafael Luque
Palladium nanoparticles supported in the nanospaces of imidazolium-based bifunctional PMOs: The role of plugs in selectivity changeover in aerobic oxidation of alcohols
ACS Catalysis, 2015, 5, 4189-4200.Full Text >>>
5) Babak Karimi, Mojtaba Khorasani, Hojatollah Vali and Rafael Luque
Control of plugging in bifunctional periodic mesoporous organosilica with imidazolium framework
via stepwise addition of silica precursors, Journal of Materials Chemistry A, 2015, 3, 6575-6585.Full Text >>>
4) Babak Karimi, Fatemeh Bakhshandeh Rostami, Mojtaba Khorasani, Dawood Elhamifar and Hojatollah Vali
Selective oxidation of alcohols with hydrogen peroxide catalyzed by tungstate ions (WO4=) supported on periodic mesoporous organosilica with
imidazolium frameworks (PMO-IL)
Tetrahedron, 2014, 70, 6114-6119. Full Text >>>
3) Babak Karimi and Mojtaba Khorasani
Selectivity adjustment of SBA-15 based tungstate catalyst in oxidation of sulfides by incorporating a hydrophobic organic
group inside the mesochannels, ACS Catalysis, 2013, 3, 1657-1664.Full Text >>>
2) Babak Karimi, Dawood Elhamifar, Omolbanin Yari, Mojtaba Khorasani, Hojatollah Vali, James H. Clark, and Andrew J. Hunt
Synthesis and characterization of alkyl-imidazolium-based periodic mesoporous organosilicas: a versatile host for the immobilization of perruthenate (RuO4-) in the aerobic oxidation of alcohols
Chemistry—A European Journal, 2012, 18, 13520-13530. Full Text >>>
1) Babak Karimi, Mohammad Gholinejad and Mojtaba Khorasani
Highly efficient three-component coupling reaction catalyzed by gold nanoparticles supported on periodic mesoporous organosilica with ionic liquid framework
Chemical Communications, 2012, 48, 8961-8963. Full Text >>>
Poster Presentation
17) 3rd International Nanotech-Eurasia Conference
Title: CO2 Valorization into Cyclic Carbonates Catalyzed by Periodic Mesoporous Organosilica with Pyridine-bis-imidazolium Frameworks Under Mild Conditions
Presenters: Sadegh Joudian and Mojtaba Khorasani
Istinye University, Istanbul, Turkey
September 2024
Oral Presentation
16) 3rd School on Chemistry Topics
Title: Conversion of Carbon Dioxide into Cyclic Carbonates Using Catalysts Supported on the Mesoporous Materials
Presenters: Sadegh Joudian and Mojtaba Khorasani
Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran
August 2023
Poster Presentation
15) 29th Iranian Organic Chemistry Conference
Title: CO2 Conversion by Nitrogen-Rich Covalent Triazine Framework
Presenters: Mohaddese Rashvand and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Poster Presentation
14) 29th Iranian Organic Chemistry Conference
Title: CO2 Conversion by Ionic liquid-Decorate Covalent Triazine Framework
Presenters: Niloofar Abbassi and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Poster Presentation
13) 29th Iranian Organic Chemistry Conference
Title: Covalent Triazine Framework as Catalyst Support for CO2 Utilization
Presenters: Mozhdeh Pourmansouri and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Poster Presentation
12) 29th Iranian Organic Chemistry Conference
Title: Supported Ni(II) on Mesoporous Organosilica Nanoparticles for CO2 Conversion
Presenters: Tohid Nouri and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Poster Presentation
11) 29th Iranian Organic Chemistry Conference
Title: Application of Periodic Mesoporous Organosilica with Imidazolium Frameworks for CO2 Conversion
Presenters: Sadegh Joudian and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Poster Presentation
10) 29th Iranian Organic Chemistry Conference
Title: Novel Hollow Mesoporous Organosilica Nanoparticle Decorated with Imidazolium Units (ImHMON) as Recoverable Catalyst for CO2 Conversion
Presenters: Ghazale Anvarian-Asl and Mojtaba Khorasani
University of Qom, Qom, Iran
November 2023
Oral Presentation
9) 3rd School on Chemistry Topics
Title: Conversion of Carbon Dioxide into Cyclic Carbonates Using Catalysts Supported on the Mesoporous Materials
Speaker: Mojtaba Khorasani
Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran
August 2023
Oral Presentation
8) Weekly Seminars of the Schools of Nano Science and Physics
Title: Valorization of Carbon Dioxide to Cyclic Carbonates Using Mesoporous Silica/Organosilica Materials
Speaker: Mojtaba Khorasani
Institute for Research in Fundamental Sciences (IPM), Tehran, Iran
July 2022
Poster Presentation
7) 21st ICS International Chemistry Congress
Title: Mesoporous Silica Nanoparticle Supported Iron Catalyst for CO2 Cycloaddtion to Epoxides
Presenters: Tohid Nouri and Mojtaba Khorasani
Azarbaijan Shahid Madani University, Tabriz, Iran
July 2022
Poster Presentation
6) 21st ICS International Chemistry Congress
Title: Coupling of CO2 with Epoxides by Periodic Mesoporous Organosilica with Ionic Liquid Frameworks under Solvent and Metal-Free Conditions
Presenters: Sadegh Joudian,Babak Karimi and Mojtaba Khorasani
Azarbaijan Shahid Madani University, Tabriz, Iran
July 2022
Poster Presentation
5) 21st ICS International Chemistry Congress
Title: Boosting the Quaternary Ammonium Halides Catalyzed CO2 Coupling with Epoxides on the Hollow Mesoporous Silica Sphere
Presenters: Ghazale Anvarian-Asl , Arian Ajal-Afshar, Masoumeh Razaghi and Mojtaba Khorasani
Azarbaijan Shahid Madani University, Tabriz, Iran
July 2022
Poster Presentation
4) 21st ICS International Chemistry Congress
Title: Efficient CO2 Fixation Catalyzed by Ionic Liquid Supported on the Magnetic Yolk-shell Mesoporous Silica
Presenters: Sanaz Asgarloo and Mojtaba Khorasani
Azarbaijan Shahid Madani University, Tabriz, Iran
July 2022
Poster Presentation
3) 21st ICS International Chemistry Congress
Title: Magnetic Mesoporous Oraganosilica Nanoparticle with Pyridine-Dicarboxamide units: Application as Catalyst Support for CO2 Fixation
Presenters: Kosar sadat Hoseini, Masoumeh Razaghi and Mojtaba Khorasani
Azarbaijan Shahid Madani University, Tabriz, Iran
July 2022
Oral Presentation
2) Weekly Seminars of the Schools of Nano Science and Physics
Title: Periodic Mesoporous Organosilica with Bulky Functional Groups within Frameworks, from Bulk to Especial Morphology
Speaker: Mojtaba Khorasani
Institute for Research in Fundamental Sciences (IPM) Tehran, Iran
July 2020
Oral Presentation
1) Catalysis, Chemometrics and Renewable Energy (Workshop)
Title: Ordered Mesoporous Silica/Organosilica as Catalyst Support
Speaker: Mojtaba Khorasani
Salahaddin University, Erbil, Iraq
April 2019